Sixteen other participants will look to book their place to the 2016 Australian Open quarterfinals, chief among them Madison Keys and Andy Murray.
On the men's side, Novak Djokovic, Roger Federer, Tomas Berdych and Kei Nishikori have already secured their place in the final eight, securing victories in the fourth round on Saturday and Sunday.
On the women's side, Serena Williams, Maria Sharapova, Carla Suarez Navarro and Agnieszka Radwanska managed the same.
Below are the complete matchups and live stream information for Monday's action.
Women's Singles
No. 7 Angelique Kerber vs. Annika Beck, 11:00 a.m. AEDT
Rod Laver Arena, a free live stream can be found here.
No. 14 Victoria Azarenka vs. Barbora Strycova, 1:00 p.m. AEDT
Rod Laver Arena, a free live stream can be found here.
No. 21 Ekaterina Makarova vs. Johanna Konta, 6:00 p.m. AEDT
Margaret Court Arena, a free live stream can be found here.
No. 15 Madison Keys vs. Shuai Zhang, 10:00 p.m. AEDT
Rod Laver Arena, a free live stream can be found here.
Men's Singles
No. 23 Gael Monfils vs. Andrey Kuznetsov, 1:00 p.m. AEDT
Margaret Court Arena, a free live stream can be found here.
No. 4 Stan Wawrinka vs. No. 13 Milos Raonic, 2:00 p.m. AEDT
Rod Laver Arena, a free live stream can be found here.
No. 8 David Ferrer vs. No. 10 John Isner, 6:30 p.m. AEDT
Hisense Arena, a free live stream can be found here.
No. 2 Andy Murray vs. No. 15 Bernard Tomic, 7:00 p.m. AEDT
Rod Laver Arena, a free live stream can be found here.
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